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ChemInform Abstract: Control of Remote Stereochemistry Using Phosphine Oxides: Formal Synthesis of any Stereoisomer Diol (RR, RS, SR or SS) Bearing 1,5-Related Stereogenic Centers Across an E Double Bond.

✍ Scribed by Adam Nelson; Stuart Warren

Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Alkenyl Diols by E-Selective Horner—Wittig Elimination: Formal Synthesis of any Isomer (RR, RS, SR or SS) Bearing 1,5-Related Stereogenic Centers Across an E Double Bond.
✍ A. NELSON; S. WARREN 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB

Alkenyl Diols by E-Selective Horner-Wittig Elimination: Formal Synthesis of any Isomer (RR, RS, SR or SS) Bearing 1,5-Related Stereogenic Centers Across an E Double Bond. -A flexible strategy for the synthesis of (E)-alkenyl 1,5-diols [cf. (IV)] bearing related stereogenic centers is presented. Oxi