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ChemInform Abstract: Contributions to the Chemistry of Phosphorus. Part 241. Reaction of Diphosphane(4) with Liquid Ammonia and with Amines — A New Route to Polyphosphides and Hydrogen Polyphosphides.

✍ Scribed by M. Baudler; P. Winzek

Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Contributions to the Chemistry of Phosphorus. Part 241. Reaction of Diphosphane(4) with Liquid Ammonia and with Amines -A New Route to Polyphosphides and Hydrogen Polyphosphides.

-The reaction of P 2 H 4 with ethylenediamine (-76→+10 • C, 2h) yields the enH + salts of (VI), (V), and (IV) in 51, 36, and 13% yield, resp. (all yields are based on 31

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