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ChemInform Abstract: Construction of Linked Nitrogen Heterocycles by Palladium(0)-Catalyzed Intramolecular Domino Cyclization of 2-Alkynylaziridines Bearing a 2-Aminoethyl Group via Ring Expansion with Isocyanate.

✍ Scribed by Akinori Okano; Shinya Oishi; Tetsuaki Tanaka; Nobutaka Fujii; Hiroaki Ohno


Publisher
John Wiley and Sons
Year
2010
Weight
44 KB
Volume
41
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

The Pd‐catalyzed reaction of alkynylaziridines of type (I) and (V) with isocyanates provides a new approach to pyrrolinylimidazolidinones and/or imidazolidinyldiazepinones depending on the nature of substituents and conditions used.