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ChemInform Abstract: Construction of Eight-Membered Carbocycles by Palladium-Catalyzed [4 + 4] Cycloaddition of Vinylallenes.

✍ Scribed by Masahiro Murakami; Kenichiro Itami; Yoshihiko Ito

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

Single-Step Construction of a Nine-Membe
Single-Step Construction of a Nine-Membered Carbocycle by a New [4+4+1] Cycloaddition
✍ Masahiro Murakami; Kenichiro Itami; Yoshihiko Ito πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 114 KB πŸ‘ 1 views

A palladium catalyst serves as a template for the assembly of a nine-membered carbocycle from two molecules of vinylallene and one molecule of carbon monoxide [Eq. (a)]. This unprecedented [4+4+1] cycloaddition is in marked contrast to the [4+1] cycloaddition mediated by rhodium(I) catalysts.

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