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ChemInform Abstract: Construction of cis-Fused Bicyclo(n.3.0) Systems via Diels-Alder Reaction-Oxidation Sequence.

✍ Scribed by G. BABU; V. SRIDAR


Book ID
112038193
Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
27
Category
Article
ISSN
0931-7597

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✍ M. LAUTENS; E. FILLION πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 34 KB πŸ‘ 2 views

The substituted dioxacyclic compounds (III) and (XI) are synthesized via the inter-and intramolecular "pincer" Diels-Alder reaction. The first ring-opening reaction of these compounds is significantly faster than the second. Treatment of tetracycle (IV) with BuLi at higher temperatures provides the