ChemInform Abstract: Conjugate Addition of Lithiated (S)-4-Isopropyl-3-[(methylthio)methyl]-5,5-diphenyloxazolidin-2-one to Cinnamoyl Derivatives: Preparation of Enantiomerically Pure 1,4-Diols.
β Scribed by Christoph Gaul; Dieter Seebach
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 41 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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Enantiomerically Pure 3-Substituted 2-Phenylprolines by Caesium Fluoride/Tetramethoxysilane Mediated 1,4-Addition of (3S,5R)-Diphenylmorpholin-2-one to Acrylates. -In continuation of the asymmetric synthesis of nonproteinogenic amino acids, the silane-mediated 1,4-addition of acrylates (II) to the