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ChemInform Abstract: Conjugate Addition of Grignard Reagents to N-(α,β-Unsaturated)acylpyrazoles. Diastereoselective β-Alkylation Using 3-Phenyl-l-menthopyrazole.

✍ Scribed by C. KASHIMA; K. TAKAHASHI; K. FUKUSAKA; A. HOSOMI


Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Catalytic Enantiose
✍ Motomu Kanai; Yuichi Nakagawa; Kiyoshi Tomioka 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB 👁 2 views

Catalytic Enantioselective Conjugate Addition of Grignard Reagents to Cyclic α,β-Unsaturated Carbonyl Compounds. -The outcome of the title reaction is influenced by many factors such as amount and structure of the chiral phosphine, copper salt, Grignard reagent, as well as the solvent used.