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ChemInform Abstract: Conformational Distribution of the Potentially Neurotoxic Metabolite of Haloperidol, HPP+, by NMR Spectroscopy, X-Ray Crystallography, and Molecular Dynamics Simulations.

✍ Scribed by F. OOMS; J. WOUTERS; F. DURANT; N. JUN. CASTAGNOLI; C. VAN'T LAND; G. DOCKENDOLF; T. GLASS; C. J. VAN DER SCHYF


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis


1998 structure structure (organic substances) K 9000

13 -035

Conformational Distribution of the Potentially Neurotoxic Metabolite of Haloperidol, HPP + , by NMR Spectroscopy, X-Ray Crystallography, and Molecular Dynamics Simulations.

-The chlorophenyl and pyridinium rings of neurotoxic pyridinium metabolite HPP + (I) are not strictly coplanar and the butyryl chain shows a high degree of mobility. The most stable structures adopt conformations corresponding either to gauche or trans rotamers. -(OOMS, F.;