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ChemInform Abstract: Condensation of Dimethyl-3-methylglutaconate with α-Aminoaldehydes: A Straightforward Synthesis of New 2-Substituted Statines.

✍ Scribed by N. PIVETEAU; P. AUDIN; J. PARIS

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Condensation

of Dimethyl-3-methylglutaconate with α-Aminoaldehydes: A Straightforward Synthesis of New 2-Substituted Statines.

-The reaction of the zinc enolate derived from diester (I) with chiral amino aldehydes (II) is investigated. At low temperature formation of undesired lactones is avoided and anti-2-substituted γ-amino-β-hydroxyesters (III) are isolated as main products. -(PIVETEAU, N.; AUDIN, P.; PARIS,

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