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ChemInform Abstract: Concave Reagents. Part 26. Concave Pyridines for Selective Acylations of Polyols.

✍ Scribed by U. LUENING; S. PETERSEN; W. SCHYJA; W. HACKER; T. MARQUARDT; K. WAGNER; M. BOLTE

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

1998 catalysis, phase-transfer catalysis catalysis, phase-transfer catalysis O 0020 35 -039 Concave Reagents. Part 26. Concave Pyridines for Selective Acylations of Polyols.

-Macrocyclic pyridines, e.g. (I) and (II), are powerful catalysts for selective acylation of very similar hydroxyl groups in polyols, e.g. selective acylation in O-2 position of methyl glucoside (III) with both free hydroxyl groups being secondary and equatorial.

-(LUENING, U.;

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