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ChemInform Abstract: Comparing Condensations of Phosphonium- and Arsonium Ylides of γ-Acetoacetate, γ-Crotonate and Related Ylides with Carbonyl Compounds.

✍ Scribed by Cornelis M. Moorhoff

Publisher: John Wiley and Sons
Year: 2010
Weight: 25 KB
Volume: 33
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200221256

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Part 3. Photoreactions of α,β-Unsaturated γ,δ-Epoxy Dinitrile, α-Cyano Ester, and Diester with Various Dipolarophiles. -Photolysis of the dinitrile (I) generates a carbonyl ylide which undergoes 1,3-dipolar cycloaddition with enol ethers [cf. (II)] to give cycloadducts (III) and (IV) in low yields.