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ChemInform Abstract: Combination of Rearrangement with Metallic and Organic Catalyses — A Step- and Atom-Economical Approach to α-Spirolactones and -lactams.

✍ Scribed by Thomas Boddaert; Yoann Coquerel; Jean Rodriguez

Publisher: John Wiley and Sons
Year: 2012
Weight: 57 KB
Volume: 43
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201208125

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## Abstract A general synthetic route to α‐spirolactones and ‐lactams from 2‐diazo‐1,3‐dicarbonyl compounds, (homo)allylic alcohols or amines and acrylic derivatives, involving a single consecutive reaction consisting of a Wolff rearrangement/α‐oxo ketene trapping/cross metathesis/Michael addition

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