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ChemInform Abstract: Cobalt-Catalyzed Intermolecular [2 + 2 + 2] Cycloaddition for the Synthesis of 1,3-Cyclohexadienes.

✍ Scribed by Gerhard Hilt; Anna Paul; Klaus Harms


Publisher
John Wiley and Sons
Year
2008
Weight
43 KB
Volume
39
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Cobalt- Catalyzed [
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Cobalt-Catalyzed [4 + 2 + 2] Cycloadditions of Bicyclo[2.2.2]octadienes. -Norbornadiene (I) and the benzobarrelenes (IV) undergo cobalt-catalyzed [4 + 2 + 2] cycloaddition with the dienes (II) or (VI) to give the corresponding adducts. In contrast, analogous reaction of the bicyclo[3.2.1]octadeine