ChemInform Abstract: C—N and C—S Bond Forming Cross Coupling in Water with Amphiphilic Resin-Supported Palladium Complexes.
✍ Scribed by Yoshinori Hirai; Yasuhiro Uozumi
- Publisher
- John Wiley and Sons
- Year
- 2012
- Weight
- 39 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
Carbon—nitrogen and carbon—sulfur bond forming reactions of haloarenes (I) and (VI) with secondary amines (II) and benzenethiols (IV) and (VII) are performed under heterogeneous conditions utilizing immobilized palladium complexes coordinated with a amphiphilic resin‐supported phosphane ligand to provide aryl(dialkyl)amines (III) and diaryl sulfides (V) and (VIII) in satisfactory to very good yields.
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