ChemInform Abstract: Cinchona Alkaloids/TMAF Combination-Catalyzed Nucleophilic Enantioselective Trifluoromethylation of Aryl Ketones.
β Scribed by Satoshi Mizuta; Norio Shibata; Surendar Akiti; Hiroyuki Fujimoto; Shuichi Nakamura; Takeshi Toru
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 46 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Asymmetric 1,4βMichael additions of malononitrile and nitromethane to a wide spectrum of Ξ±,Ξ²,Ξ³,Ξ΄βunsaturated aryl ketones assisted by organocatalysis by bifunctional cinchona alkaloids is developed.
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