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ChemInform Abstract: Chromium Carbenes as Substrates in Cyclopropanation Reactions: 1,4- vs 1,2-Addition in the Reaction of Sulfur Ylides and α,β- Unsaturated Alkoxychromium(0) Carbenes.

✍ Scribed by B. ALCAIDE; L. CASARRUBIOS; G. DOMINGUEZ; M. A. SIERRA; J. JIMENEZ-BARBERO


Book ID
112020537
Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
26
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Diverse Cycloadditi
✍ Y. XU; W. R. JUN. DOLBIER 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB 👁 2 views

Diverse Cycloaddition Chemistry Leading to Overall Michael Addition in the Reactions of 1,1-Bis(dimethylamino)-2,2-difluoroethene with α,β-Unsaturated Aldehydes, Ketones, Esters, and Nitriles. -The freshly prepared difluoro ketene aminal (I) reacts with α,β-unsaturated aldehydes or ketones via [4 +