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ChemInform Abstract: Chiral β-Lithio Enol Ethers: Synthesis and Properties.

✍ Scribed by V. GODEBOUT; S. LECOMTE; F. LEVASSEUR; L. DUHAMEL

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Chiral β-Lithio Enol Ethers: Synthesis and Properties. -Sequential treatment of ethyl vinyl ether (I) with bromine and the chiral alcohols (II) gives the mixed bromoacetals (III) which are readily transformed to mainly the Z-bromo enol ethers (IV). These bromoenolderivatives are suitable precursors for the chiral Z-alkyl derivatives (VII), the corresponding debrominated products (V) or the acetyl derivative (IX). -(GODEBOUT, V.; LECOMTE, S.;

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