ChemInform Abstract: Chiral Thiophosphoramidate-Catalyzed Asymmetric Michael Addition of Ketones to Nitro Olefins.
β Scribed by Aidang Lu; Ronghua Wu; Youming Wang; Zhenghong Zhou; Guiping Wu; Jianxin Fang; Chuchi Tang
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0931-7597
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## Abstract The new thiophosphoramide (I) is used as efficient bifunctional organocatalyst for the asymmetric Michael addition of cyclic ketones to nitro olefins.
## Abstract The title bifunctional organocatalyst promotes the Michael addition of both alkyl and aryl nitro olefins to acetone and cyclopentanone; however, no reactions are observed with cyclohexanone.
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