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ChemInform Abstract: Chiral Sodium Phosphate Catalyzed Enantioselective 1,4-Addition of TMSCN to Aromatic Enones.

โœ Scribed by Jingya Yang; Shaoxiang Wu; Fu-Xue Chen

Publisher
John Wiley and Sons
Year
2011
Weight
29 KB
Volume
42
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Abstract

The process offers generally moderate eeโ€ฒs only.

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Enantioselective Copper-Catalyzed 1,4-Addition of Organozinc Reagents to Enones Using Chiral Oxazoline-Phosphite Ligands. -The enantioselective 1,4-addition of organozinc reagents to ฮฑ,ฮฒ-unsaturated ketones in the presence of chiral P,N-ligands (I) with a binaphthyl phosphite group and an oxazoline