Detection of chiral recognition in various intermolecular interaction systems using mass spectrometry has become important for the modern fields of analytical chemistry, organic chemistry, and biochemistry due to the characteristic nature of the rapid method and the trace amount needed. This review
ChemInform Abstract: Chiral Recognition Detected by Fast Atom Bombardment Mass Spectrometry
β Scribed by M. SAWADA
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 24 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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An intensity function combining peak intensities in the same manner as that in which equilibrium constants combine ion activities is suggested for characterization of enantioselectivity by fast-atom bombardment mass spectrometry. The intensity function combined with the use of two internal standards
A chiral effect has been observed for formation of protonated dimers of dialkyl tartrates under fast atom bombardment, analogous to the chemical ionization behaviour reported previously. Homochiral dimers show greater stability than the heterochiral dimers, as is evidenced by their enhanced formatio