ChemInform Abstract: Chiral (ON)Ru-Salen Catalyzed Cyclopropanation: High cis- and Enantioselectivity.
β Scribed by Tatsuya Uchida; Ryo Irie; Tsutomu Katsuki
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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Ru(II)-Catalyzed Asymmetric Cyclopropanation Using Chiral Diphenylphosphino(oxazolinyl)quinoline Ligands. -N,N,P-chelates (I) are investigated as chiral ligands in intermolecular and intramolecular asymmetric Ru-catalyzed cyclopropanation reactions. A dramatic influence of the oxazoline ring substi