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ChemInform Abstract: Chiral Diene-Phosphine Tridentate Ligands for Rhodium-Catalyzed Asymmetric Cycloisomerization of 1,6-Enynes.

✍ Scribed by Takahiro Nishimura; Yuko Maeda; Tamio Hayashi

Publisher: John Wiley and Sons
Year: 2011
Weight: 79 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201148161

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✦ Synopsis

Abstract

The reaction is carried out with nitrogen‐bridged 1,6‐enynes to afford the chiral 3‐azabicyclo[4.1.0]heptenes with high enantioselectivities.

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