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ChemInform Abstract: Chiral Biscinchona Alkaloid Promoted Asymmetric Allylic Alkylation of 3-Substituted Benzofuran-2(3H)-ones with Morita—Baylis—Hillman Carbonates.

✍ Scribed by Cong Liu; Bo-Xuan Tan; Jia-Lu Jin; Yue-Yan Zhang; Nan Dong; Xin Li; Jin-Pei Cheng


Publisher
John Wiley and Sons
Year
2011
Weight
52 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

The alkaloid efficiently promotes the coupling of 3‐substituted benzofuranones with carbonates giving 3,3‐disubstituted benzofuranones with moderate to high diastereo‐ and enantioselectivity.