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ChemInform Abstract: Chiral Azacrown Ethers Derived from D-Glucose as Catalysts for Enantioselective Michael Addition.

✍ Scribed by P. BAKO; T. KISS; L. TOEKE

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Chiral Azacrown Ethers Derived from D-Glucose as Catalysts for Enantioselective Michael Addition.

-Application of chiral glucose-derived monoaza-crown ethers such as (I)-(III) as catalysts for the enantioselective Michael addition of 2-nitropropane to chalcone (IV) is investigated. Best results are obtained with (III) which gives the corresponding adduct in 90% e.e.

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