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ChemInform Abstract: Chiral Arene—Cr(CO)3 Complexes in Organic Synthesis: A Short Enantioselective Total Synthesis of Putative Helioporin D.

✍ Scribed by T. GELLER; H.-G. SCHMALZ; J. W. BATS


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Total Synthesis of
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Total Synthesis of (-)-Macrocarpal C. Stereoselective Coupling Reaction with a Novel Hexasubstituted Benzene Cr(CO) 3 Complex as a Biomimetic Chiral Benzyl Cation Equivalent. -The use of the novel chiral complex (II) allows for the stereocontrolled coupling with silyldienol ether (III) to obtain aft