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ChemInform Abstract: Chiral [1]Rotaxanes: X-Ray Structures and Chiroptical Properties.

✍ Scribed by Carin Reuter; Christian Seel; Martin Nieger; Fritz Voegtle

Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
31
Category
Article
ISSN
0931-7597

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The synthesis of a topologically chiral in,out-bis-sulfonamide catenane and its "dimer" are reported. The structures of the amide wheel and of the catenane were resolved by X-ray analysis. NMR-titration of the monosulfonamide-wheel yielded conclusive association constants supporting the proposed reg