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ChemInform Abstract: Chemoselective Reduction of α,β-Epoxy Carbonyl Compounds to β-Hydroxy Carbonyl Compounds (Aldols and Their Analogues) by Organoseleniums and Its Applications to Natural Product Synthesis

✍ Scribed by Toshio Suzuki; Masaaki Miyashita


Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: The Organoselenium-
✍ M. MIYASHITA; T. SUZUKI; M. HOSHINO; A. YOSHIKOSHI 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 46 KB 👁 1 views

The Organoselenium-Mediated Reduction of α,β-Epoxy Ketones, α,β-Epoxy Esters, and Their Congeners to β-Hydroxy Carbonyl Compounds: Novel Methodologies for the Synthesis of Aldols and Their Analogues. -The reduction of the title compounds with Na[PhSeB(OEt) 3 ] (prepared by reduction of (PhSe) 2 wi