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ChemInform Abstract: Chemoenzymatic Synthesis of (S)-2-Cyanopiperidine, a Key Intermediate in the Route to (S)-Pipecolic Acid and 2-Substituted Piperidine Alkaloids.

โœ Scribed by S. NAZABADIOKO; R. J. PEREZ; R. BRIEVA; V. GOTOR

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
29
Category
Article
ISSN
0931-7597

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Microbially-Aided Preparation of (S)-2-Methoxycyclohexanone Key Intermediate in the Synthesis of Sanfetrinem. -It is shown that the enantiomerically pure (S)-carbinol (I), obtained by baker's yeast-mediated reduction of 2-benzylcyclohexanone, can be transformed efficiently into the title ketone (S)