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ChemInform Abstract: Chemoenzymatic Synthesis of Enantiopure 1-Azafagomine.

✍ Scribed by Xifu Liang; Mikael Bols

Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
31
Category
Article
ISSN
0931-7597

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For the first time the two enantiomeric forms of the glycosidase inhibitor 1-azafagomine have been synthesised starting from d-and l-xylose. d-Xylose was converted to the 2,3,5tribenzylfuranose, which upon reductive amination with tert-butyl carbazate gave the protected 1-hydrazino-1-deoxypentitol i