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ChemInform Abstract: Chemoenzymatic Epoxidation of Alkenes by Dimethyl Carbonate and Hydrogen Peroxide.

✍ Scribed by Mark Ruesch gen. Klaas; Siegfried Warwel

Book ID
101893458
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Chemoenzymatic Epoxidation of Alkenes by Dimethyl Carbonate and Hydrogen Peroxide.

-Lipase-catalyzed perhydrolysis of dimethyl carbonate with hydrogen peroxide generates monoperoxy carbonic acid methyl ester which is used in situ for a selective and efficient epoxidation of various olefins. The unstable ester decomposes to MeOH and CO 2 . -(RUESCH

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