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ChemInform Abstract: Chemoenzymatic Deracemization of (.+-.)-2,2-Disubstituted Oxiranes.

✍ Scribed by R. V. A. ORRU; S. F. MAYER; W. KROUTIL; K. FABER


Publisher
John Wiley and Sons
Year
2010
Weight
40 KB
Volume
29
Category
Article
ISSN
0931-7597

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✍ Eirik Sundby; Jarle Holt; Anders Vik; Thorleif Anthonsen 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 106 KB

## Abstract Lipase‐catalyzed transesterifications and biological reductions were used to obtain the (__S__)‐enantiomers of 3‐chloro‐1‐(1,3‐dithian‐2‐yl)‐2‐propanol and 1‐(1,3‐dithian‐2‐yl)‐3‐fluoro‐2‐propanol and their (__R__)‐acetates. (__S__)‐3‐Chloro‐1‐(1,3‐dithian‐2‐yl)‐2‐propanol and (__R__)‐3