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ChemInform Abstract: Chemistry of Free Cyclic Vicinal Tricarbonyl Compounds (“1,2,3-Triones”). Part 1. Reaction of Diazomethane and Its Derivatives with 5,5-Dimethylcyclohexane-1,2,3-trione (=“Oxo-dimedone”) and Related Cyclohexane-1,2,3-triones

✍ Scribed by Kurt Schank; Luigi La Vecchia; Carlo Lick


Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
32
Category
Article
ISSN
0931-7597

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Synthesis and Transamination of Enaminones: Derivatives of 1-Phenyl-4-(phenylhydroxymethylidene)-pyrrolidine-2,3,5-trione. -The reaction of pyrrolidine-2,3,5-trione (I) with difunctional bases leads to a mixture of tautomeric Schiff bases and enaminones. Some of the products easily undergo transami