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ChemInform Abstract: Chemical Conversion of Cyclic α-Amino Acids to Cyclic α-Aminophosphonic Acids.
✍ Scribed by Mamoru Kaname; Hironori Mashige; Shigeyuki Yoshifuji
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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Many new cyclic esters of N-toluenesulfonyl ␣-aminophosphonic acids were synthesized by the three-component reaction of p-toluenesulfonamide, an aromatic aldehyde, and 2-chloro-1,3,2-benzodioxaphosphole in anhydrous benzene. Different reaction conditions have been investigated, and the related react
Synthesis of α-Substituted α-Aminophosphinic and α-Aminophosphonic Acids. -The reaction of ketoximes (I) with hypophosphorous acid affords previously unknown phosphinic acids (II), which are smoothly oxidized into the corresponding phosphonic acids (III). -(OSIPOVA, T. I.;