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ChemInform Abstract: C—H Bond Functionalization with [RuH(codyl)2]BF4 Catalyst Precursor.

✍ Scribed by Wenbo Li; Percia B. Arokiam; Cedric Fischmeister; Christian Bruneau; Pierre H. Dixneuf

Publisher
John Wiley and Sons
Year
2011
Weight
38 KB
Volume
43
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

The presented cross‐coupling reaction strongly depends on the nature of both substrates and proceeds without formation of any metal‐salt waste.

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ChemInform Abstract: Application of [Ru((R)-BINAP)(MeCN)(1-3:5,6-η-C8H11)] (BF4) as a Catalyst Precursor for Enantioselective Hydrogenations.
✍ Christopher J. A. Daley; J. A. Wiles; S. H. Bergens 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 43 KB

Application of [Ru((R)-BINAP)(MeCN)(1-3:5,6-η-C 8 H 11 )] (BF 4 ) as a Catalyst Precursor for Enantioselective Hydrogenations. -The title catalyst precursor forms under hydrogenation conditions in MeOH or acetone complexes containing the [Ru((R)-BINAP)(H)] + fragment. It acts as catalyst in the hyd