ChemInform Abstract: Ceric Ammonium Nitrate (CAN) Mediated Azidoalkoxylation of Enol Ethers and Olefins.

✍ Scribed by Subhash P. Chavan; Y. Tripura Subbarao

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 29 KB
• Volume: 30
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199939037

✦ Synopsis

Ceric Ammonium Nitrate (CAN) Mediated Azidoalkoxylation of Enol Ethers and Olefins.

-Treatment of a variety of olefins (I), (IV), and (VI) with CAN and sodium azide in alcoholic solution results in efficient azidoalkoxylation for the first time. This constitutes a practical route for the synthesis of amino acetals. -(CHAVAN, SUBHASH P.; SUBBARAO, Y.