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ChemInform Abstract: Cationic Rhodium(I) Complex-Catalyzed [3 + 2] and [2 + 1] Cycloadditions of Propargyl Esters with Electron-Deficient Alkynes and Alkenes.

✍ Scribed by Yu Shibata; Keiichi Noguchi; Ken Tanaka

Publisher: John Wiley and Sons
Year: 2010
Weight: 26 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201039038

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✦ Synopsis

Abstract

A variety of acyloxy‐substituted tertiary propargyl esters undergo the title cycloaddition reaction with acetylenedicarboxylates to give cyclopentadienetricarboxylates.

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