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ChemInform Abstract: Cationic Platinum-Complex-Catalyzed Skeletal Reorganization of Enynes.

✍ Scribed by Shuichi Oi; Issei Tsukamoto; Sotaro Miyano; Yoshio Inoue


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
32
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Sequential Cyclizat
✍ G. A. MOLANDER; W. H. RETSCH πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 31 KB πŸ‘ 1 views

Sequential Cyclization/Silylation of Enynes Catalyzed by an Organoyttrium Complex. -In the title reaction affording silylated carbocycles the diastereoselectivity can be enhanced by increasing the size of allylic substituents on the substrate. With an appropriate silane, a 1,7 enyne can also be cyc