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ChemInform Abstract: Catalyzed Aerobic Dehydrogenation of Amines and an X-Ray Crystal Structure of a Bis(benzylamine) Ruthenium(II) Porphyrin Species.

✍ Scribed by A. J. BAILEY; B. R. JAMES

Publisher: John Wiley and Sons
Year: 2010
Weight: 29 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199711049

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✦ Synopsis

Catalyzed Aerobic Dehydrogenation of Amines and an X-Ray Crystal Structure of a Bis(benzylamine) Ruthenium(II) Porphyrin Species.

-The dehydrogenation of primary and secondary amines, e.g. (I) and (V), most likely proceeds via a disproportionation reaction that generates a Ru(II) intermediate. The latter is evidenced by isolation and X-ray analysis of the title Ru(II) species. -(BAILEY, A.

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