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ChemInform Abstract: Catalytic Enantioselective Protonation of Lithium Ester Enolates Generated by Conjugate Addition of Arylthiolate to Enoates.

✍ Scribed by Katsumi Nishimura; Masashi Ono; Yasuo Nagaoka; Kiyoshi Tomioka

Publisher: John Wiley and Sons
Year: 2001
Weight: 27 KB
Volume: 32
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200115038

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Catalytic Enantioselective Addition of Enol Silanes to Ketomalonate Mediated by C 2 -Symmetric Bisoxazoline Lewis Acid Complexes. -A catalytic enantioselective addition reaction of silyl enol ethers to ketomalonate (II) in the presence of copper(II) bisoxazolines as catalysts is presented. The react