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ChemInform Abstract: Catalytic Enantioselective Michael Addition of 1-Fluoro-bis(phenylsulfonyl)methane to α,β-Unsaturated Ketones Catalyzed by Cinchona Alkaloids.

✍ Scribed by Tatsuya Furukawa; Norio Shibata; Satoshi Mizuta; Shuichi Nakamura; Takeshi Toru; Motoo Shiro


Publisher
John Wiley and Sons
Year
2009
Weight
35 KB
Volume
40
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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## Abstract Asymmetric 1,4‐Michael additions of malononitrile and nitromethane to a wide spectrum of α,β,γ,δ‐unsaturated aryl ketones assisted by organocatalysis by bifunctional cinchona alkaloids is developed.