ChemInform Abstract: Catalytic Enantioselective Hosomi—Sakurai Conjugate Allylation of Cyclic Unsaturated Ketoesters.
✍ Scribed by Manami Shizuka; Marc L. Snapper
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 56 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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📜 SIMILAR VOLUMES
## Abstract Asymmetric 1,2‐allylation of cyclic enones followed by oxy‐Cope rearrangement allows convenient access to various optically active β‐allylated cyclic ketones.
Catalytic Enantioselective Conjugate Addition of Grignard Reagents to Cyclic α,β-Unsaturated Carbonyl Compounds. -The outcome of the title reaction is influenced by many factors such as amount and structure of the chiral phosphine, copper salt, Grignard reagent, as well as the solvent used.