✦ LIBER ✦
ChemInform Abstract: Catalytic Enantioselective C—H Functionalization of Indoles with α-Diazopropionates Using Chiral Dirhodium(II) Carboxylates: Asymmetric Synthesis of the (+)-α-Methyl-3-indolylacetic Acid Fragment of Acremoauxin A.
✍ Scribed by Takayuki Goto; Yoshihiro Natori; Koji Takeda; Hisanori Nambu; Shunichi Hashimoto
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 62 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
The title reaction provides a variety of N‐Mom‐protected α‐methyl‐3‐indolylacetates (III) in moderate enantioselectivities up to 86%.