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ChemInform Abstract: Catalytic Enantioselective Alkylation of Heteroaromatic Compounds Using Alkylidene Malonates.

✍ Scribed by Wei Zhuang; Tore Hansen; Karl Anker Joergensen

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
32
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.

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Catalytic, Enantioselective Alkylations of N,O-Acetals. -The first high-yielding (73-93%) asymmetric alkylations (e.e. up to 96%) of racemic hemiacetals of type (I) with nucleophiles (II) or (V) using a chiral Cu(I)-based catalyst are presented. Several N-protecting sulfonyl groups are tested with