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ChemInform Abstract: Catalytic Asymmetric Synthesis of Chiral Tertiary Organoboronic Esters Through Conjugate Boration of β-Substituted Cyclic Enones.

✍ Scribed by I-Hon Chen; Liang Yin; Wataru Itano; Motomu Kanai; Masakatsu Shibasaki


Publisher
John Wiley and Sons
Year
2010
Weight
44 KB
Volume
41
Category
Article
ISSN
0931-7597

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Catalytic conjugate addition of a boron nucleophile (M-B) to unsaturated carbonyl substrates [1] has emerged as a novel synthetic tool to afford b-boryl carbonyl compounds, [2] an important class of organoboron compounds. While several important and efficient methodologies for conjugate boration hav