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ChemInform Abstract: Catalytic Asymmetric Syntheses of Secondary Alcohols Using cis-1-Amino- 2-indanols as Chiral Ligands.

โœ Scribed by B. DI SIMONE; D. SAVOIA; E. TAGLIAVINI; A. UMANI-RONCHI


Book ID
112022950
Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
26
Category
Article
ISSN
0931-7597

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Catalytic asymmetric synthesis of second
โœ Cristina M Bellucci; Antonio Bergamini; Pier Giorgio Cozzi; Angelo Papa; Emilio ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 529 KB

The synthesis and resolution of cis-1-amino-2-hydroxy-1,2,3,4tetrahydronaphthalene 5 by a simple and straightforward methodology has been achieved. The homochiral aminoalcohol has been used in the catalytic reduction of ketones by means of BH 3 .SMe2 affording secondary alcohols in high enantiomeric