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ChemInform Abstract: Catalytic Asymmetric Hydrosilylation of Ketones with New Chiral Ferrocenylphosphine-Imine Ligands.

โœ Scribed by T. HAYASHI; C. HAYASHI; Y. UOZUMI

Book ID
112028851
Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
27
Category
Article
ISSN
0931-7597

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Catalytic asymmetric hydrosilylation of
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New chiral ferrocenylphosphines containing an imino group on the side chain, (S)-N-alkylidene-l-[(R)-2-diphenylphosphinoferrocenyl]ethylamines, were prepared by condensation of (S)-l-[(R)-2-diphenylphosphinoferrocenyl]ethylamine with aromatic aldehydes. The imino-phosphine ligands were found to be v

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Asymmetric syntheses, especially hydrogenation, catalyzed by transition metal complexes with chiral ligands have recently attracted much interest. In most cases, phosphines having an asymmetric center at the phosphorus atom1 or those derived from L-threito12 or I-menthol3 have