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ChemInform Abstract: Catalytic Asymmetric Aziridination of α,β-Unsaturated Aldehydes.

✍ Scribed by Luca Deiana; Pawel Dziedzic; Gui-Ling Zhao; Jan Vesely; Ismail Ibrahem; Ramon Rios; Junliang Sun; Armando Cordova

Publisher
John Wiley and Sons
Year
2011
Weight
51 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

The procedure can be applied to aliphatic and aromatic enals, α‐substituted‐α,β‐unsaturated aldehydes and α,β‐disubstituted‐α,β‐unsaturated aldehydes giving trans‐aziridines in high diastereo‐ and enantioselectivity.

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ChemInform Abstract: Multicomponent Cata
ChemInform Abstract: Multicomponent Catalytic Asymmetric Aziridination of Aldehydes.
✍ Anil K. Gupta; Munmun Mukherjee; William D. Wulff 📂 Article 📅 2012 🏛 John Wiley and Sons ⚖ 48 KB

## Abstract Various aziridine‐2‐carboxylic esters are prepared with high yields and enantioselectivities from imines, generated in situ from aldehydes and the amine (I), with ethyl diazoacetate (EDA).