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ChemInform Abstract: Catalytic and Structural Features of Hydroxy and Methoxy Groups as Hemilabile Coordinating Ligands in Chiral (Diphosphane)rhodium(I) Hydrogenation Catalysts.

✍ Scribed by S. BORNS; R. KADYROV; D. HELLER; W. BAUMANN; A. SPANNENBERG; R. KEMPE; J. HOLZ; A. BOERNER


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
29
Category
Article
ISSN
0931-7597

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The influence of two threo-arranged methoxy or hydroxy structural analysis reveals that the oxygen atom of the hydroxy group is by 0.9 A ˚closer to the metal center than that groups as hemilabile ligands in seven-membered (diphosphane)Rh I chelates upon the asymmetric of the methyl ether. 31 P-NMR s