## Abstract α‐Substituted chiral ketones that have small steric and electronic differences around the reaction sites are difficult substrates to reduce with high diastereoselectivity. Metal hydride reduction of 2‐(4‐benzoylmorpholinyl) phenyl ketone and 3‐(1‐__tert__‐butoxycarbonylpiperidinyl) phen
ChemInform Abstract: Catalyst-Controlled Diastereoselection in the Hydrogenation of Heterocycloalkyl Ketones.
✍ Scribed by Masaya Akashi; Noriyoshi Arai; Tsutomu Inoue; Takeshi Ohkuma
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 36 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The individual enantiomers of substituted cyclohexyl diazoacetates (I)-(IV) or 2-octyl diazoacetates (V) matched with a configurationally suitable chiral dirhodium(II) carboxamidate catalyst provide an effective methodology for the synthesis of lactones with exceptional diastereoand regiocontrol. Th
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v