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ChemInform Abstract: Carotenoid Synthesis. Coupling Reactions. Part 1. Enol Ether and Aldol Condensations

โœ Scribed by L. LABLER; A. RUTTIMANN; A. GIGER


Publisher
John Wiley and Sons
Year
2010
Weight
24 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Unexpected Aldol Co
โœ A. L. SILVA; B. QUIROZ; L. A. MALDONADO ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 29 KB

Unexpected Aldol Condensations under Williamson Arylmethyl Ether Synthesis Conditions. -O-Methylation of 5-bromosalicylaldehyde (Ia) under standard conditions using dimethyl sulfate in refluxing acetone for 2h gives the expected methyl ether (Va) in high yield. However, prolonged reflux leads to th